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Oxidation Kinetics in Beltcoat Compound

Abstract

Because tires spend most of their lives at ambient temperature, knowledge of oxidation
kinetics in this temperature regime is very important. Oxidation has been shown to be a
key degradation mechanism in beitcoat compound governing belt edge durability in
passenger tires. The ultra-sensitive oxygen consumption technique developed by K
Gillen was used to measure oxidation kinetics of a passenger tire belt coat compound
over a wide temperature range, including ambient temperature. The ultra-sensitive
oxygen consumption technique allows accurate measurements in this lower temperature
regime, from which accurate time-temperature lifetime oxidation master curves can be
obtained. In this way, it is not necessary to extrapolate to ambient temperatures to predict
lifetime at service temperatures.

 

To obtain a full-text copy of this paper, please email Ed Terrill or visit Rubber Division, ACS at www.rubber.org

 

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